The enantiomeric excess determination and dynamic behaviour of cyclic phosphoric acids used for resolution
نویسندگان
چکیده
A method is presented to determine the enantiomeric excess (ee) of phosphoric acids 1, which are extensively used as resolving agents, by means of diastereomeric salt formation with chiral amines. The unexpected dynamic behaviour of these systems leads us to postulate a model, which we refer to as non-reciprocal behaviour.
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